Crystal structure and DFT study of bis{(S)-2-[(2-hydroxybenzyl)amino]-4-methylpentanoato-κ2 N,O}(1,10-phenanthroline-κ2 N,N′)nickel(II)
نویسندگان
چکیده
In the title compound, [Ni(C13H18NO3)2(C12H8N2)], the NiII cation shows a distorted octa-hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noate ligands. Complex mol-ecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxyl-ate and phenoxide groups, which are further connected into a three-dimensional motif.
منابع مشابه
{2-[(5-Bromo-2-oxidobenzylidene)amino-κ2 N,O]-3-methylpentanoato-κO}(1,10-phenanthroline-κ2 N,N′)copper(II) dihydrate
In the title compound, [Cu(C(13)H(14)BrNO(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is penta-coordinated in a square-pyramidal geometry. The crystal packing is stabilized by O-H⋯O hydrogen bonds.
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